green ammonia production process

For commercial production scale, potential alternatives can be based on biomass gasification and water electrolysis via renewable energy, namely biomass- and power-to-ammonia. Green ammonia is produced using CO 2 free energy sources Ammonia is one of the most highly produced inorganic chemicals. The biomass-to-ammonia reaches above 450 $/ton ammonia production cost with a payback time of over 6 years, higher than those of methane-to-ammonia (400 $/ton, 5 years). The steam cycles with three pressure levels are able to maximize the heat utilization at the system level. To achieve net-zero emission targets, the amount of carbon dioxide generated during the production process should be minimized. Green ammonia refers to ammonia, which has been produced through a process that is 100% renewable and carbon-free. To reduce the fossil-fuel consumption and the impacts of conventional ammonia production on climate change, green ammonia production processes using green hydrogen need to be investigated. The company’s approach will focus on green ammonia production, which refers to ammonia produced through a carbon-free process, and low-carbon ammonia, which relates to ammonia produced by conventional processes but with CO 2 removed through carbon capture and sequestration (CCS) and other certified carbon abatement projects. By continuing you agree to the use of cookies. In this paper, techno-economic feasibility of these two green ammonia production processes are investigated and compared with the state-of-the-art methane-to-ammonia process, considering system-level heat integration and optimal placement of steam cycles for heat recovery. Power-to-ammonia process can achieve the highest system efficiency of over 74%. DOI: 10.1016/j.joule.2020.10.006 Journal information: Joule Existing process: Using a Large-scale centralized Haber-Bosch synthesis utilizing steam methane reforming across (SMR-HB). Green ammonia, which is produced entirely from sustainable, carbon-neutral inputs, like biomass or renewable electricity, is now in development in academic institutions and R&D centers around the world. from electrolysis production linked to a wind farm)? We offer a full range of technical services, backed by deep insight and decades of hands-on experience. Medium-term: All electric distributed Haber-Bosch process at smaller scale, utilizing electrolysis and a nitrogen air separation stage (As shown above in figure 2) (E-HB). Copyright © 2020 Elsevier B.V. or its licensors or contributors. Ammonia production has become one of the most important industries in the world. We provide unmatched insight into how to operate a dynamic ammonia … SOEC technology has synergies with the ammonia synthesisand will provide the most energy-efficient green ammonia. There will be a market for both green methanol and green ammonia depending on the use or market. Green ammonia is intended to be used in the production of carbon-neutral fertiliser products, decarbonising the food value chain, and also has potential as a future climate-neutral shipping fuel. The steady state mass and energy balance of each process in the manufacturing of green urea from different process paths are performed using Aspen Plus. The biomass-to-ammonia is the most exothermic but is largely limited by the large heat requirement of acid gas removal. hbspt.cta._relativeUrls=true;hbspt.cta.load(2115834, '0724f121-6dac-421d-a996-db39026ef634', {}); What does dynamic mean? More information: Dae-Kwang Lim et al. With a reference ammonia production of 50 kton/year, the results show that there are trade-offs between the overall energy efficiency (LHV) and ammonia production cost for all three cases. The Haber-Bosch process, which converts hydrogen and nitrogen to ammonia, could be one of the most important industrial chemical reactions ever developed. The former generally uses entrained flow gasifier due to low CO2 and almost no tar, and air separation units are shared by the gasifier and ammonia synthesis. By 2024, the ammonia engines (Internal Combustion Engines) will be available from MAN ES. We supply more than 150 different catalysts and have the capability to design and manufacture custom catalysts for specific tasks. The recent decline of production costs and its potential as an energy vector warrant investigation of whether green ammonia production is commercially competitive. Green ammonia entirely from renewable sources Topsoe has developed process technologies and catalysts for production of green ammonia entirely from renewable sources – wind, water, and air. Browse other articles of this reference work: BROWSE BY TOPIC; … Topsoe LiveShare webinar - "Green ammonia – challenges, opportunities, future"How will the shift towards electrified ammonia production occur? Reducing the … In conclusion, the development of “green” ammonia production methods is an environmental imperative as one of the measures for reaching net-zero carbon dioxide emissions. NOx will be reduced to low level by deNOx, which is already referenced by MAN ES and Haldor Topsoe. The power-to-ammonia is currently not economically feasible due to high stack costs and electricity prices; however, it can be competitive with a payback time of below 5 years with mass production of solid-oxide industry and increased renewable power penetration. Green ammonia uses renewable energy instead of natural gas or coal for producing hydrogen; hence, is an effective way to reduce greenhouse emissions. Green ammonia entirely from renewable sourcesTopsoe has developed process technologies and catalysts for production of green ammonia entirely from renewable sources – wind, water, and air. The ammonia produced by utilizing renewables via the Haber-Bosch process, also known as green ammonia could help reduce above mentioned vast emissions in the ammonia industry. Power-to-ammonia will be competitive (payback times below 5 years) with solid-oxide fuel cells. Perfecting a method whereby green energy is produced with the only byproducts being hydrogen and ammonia will be critical in the movement towards a clean and safer future for energy. Apart from being used for fertilizer to feed the world, ammonia has another great potential – when produced sustainably, it can become an emission-free green fuel or be used as energy storage and carrier.Topsoe has developed process technologies and catalysts for production of green ammonia from renewable sources – wind, water, and air. Ammonia—a renewable fuel made from sun, air, and water—could power the globe without carbon. Avoiding highly expensive hydrogen storages will of course make the green ammonia plants more economically feasible and safer.Dynamic means constant synthesis loop pressure for the full operating range 10-100%. Over the past 70 years, Topsoe has earned a reputation for being a trusted supplier to the ammonia industry. How fast can ammonia plant react on hydrogen profiles (e.g. green ammonia. CO2 taxes are being discussed but there are uncertainties on when and how much. “Our existing scale and commitment to produce green … Green ammonia is no different from blue ammonia except that the hydrogen fuel generated is from the byproduct of solely green fuel methods. With the proven track record in the industry and a deep understanding of the science behind ammonia, we are your trusted partner, delivering highly efficient solutions for a robust and highly flexible ammonia synthesis operation. Yara International ASA (Oslo, Norway) has announced plans for 500,000 metric tons per year (m.t./yr) of green ammonia production in Norway, powering emission-free shipping fuels and decarbonized food solutions. It can react to any change in hydrogen production from the electrolyzers.In terms of using ammonia for maritime usage, will there need to be major retrofitting for NOx control or is there a prediction that fuel cells will be used instead of combustion? One emerging solution is to use the green hydrogen at or near its point of production make green ammonia (the formula for ammonia is NH3). Green ammonia production processes are investigated and compared with state-of-the-art methane-to-ammonia process. Such green hydrogen can be synthesise further in ammonia synthesis plant to produce green ammonia by using SOE technology. The company’s approach will focus on green ammonia production, which refers to ammonia produced through a carbon-free process, and low-carbon ammonia, which relates to ammonia produced by conventional processes but with CO 2 removed through carbon capture and sequestration and other certified carbon abatement projects. This allows the storage of electricity when production exceeds demand. And when the market demand for green ammonia increases, any existing ammonia plant can be further revamped above 10% green production.With our patented green ammonia solutions, established fertilizer producers can tap into the new green ammonia market and maintain current production capacity while adding green ammonia to the mix. 12, 2018 , 2:00 PM. Solid Acid Electrochemical Cell for the Production of Hydrogen from Ammonia, Joule (2020). Watch the webinar to learn about: In August 2020, Alfa Laval, Hafnia, Haldor Topsoe, Vestas, and Siemens Gamesa issued the report “Ammonfuel – an industrial view of ammonia as a marine fuel” based on own industrial expertise and input from a list of competent industrial players. A team from KU Leuven and the University of Antwerp in Belgium has developed a new process that is suitable for the distributed, small-scale production of “green” ammonia. Green ammonia production is where the process of making ammonia is 100% renewable and carbon-free. Existing international shipping routes for ammonia overlap with potential green hydrogen export flows, and a network of ports worldwide can handle ammonia at industrial scale. 2. More information can be found in our Ammonfuel report.What is your opinion on green methanol and which one will become more prevalent in the future (ammonia economy vs. methanol economy)? The steam cycles with three pressure levels are … Power-to-ammonia process can achieve the highest system efficiency of over 74%. Green ammonia refers to ammonia which is produced through a completely renewable and carbon-free process. Topsoe has technology solutions for both methanol and ammonia as well as other eFuels such as gasoline, diesel, and jet-fuel.How high does a future CO2 tax need to be to make green ammonia competitive for marine use? Green ammonia production processes are investigated and compared with state-of-the-art methane-to-ammonia process. Ammonia production has increased steadily since 1946 (Figure 2), and it is estimated that the annual production of ammonia is worth more than $100 billion, with some plants producing more than 3,000 m.t./day of NH3. Green Ammonia Production. The current production of ∼180 MT/year is predicted to increase to ∼270 MT/year by 2050 (C. Philibert, 2017, NH3 Event, conference), understandable given that over 80% of all … The Siemens green ammonia test plant uses wind power to convert hydrogen and nitrogen to ammonia. Click to Get Sample Copy of Report @ … What is green ammonia? There are numerous large-scale ammonia production plants worldwide, producing a total of 144 million tonnes of nitrogen (equivalent to 175 million tonnes of ammonia) in 2016. Economic Aspects of Green Ammonia Production: 8: Nonconventional Technologies : 8.1: Nonconventional Heterogeneous Catalysis: 8.2: Absorbent‐ and Adsorbent‐Enhanced Haber–Bosch Processes: 9: Role of Ammonia in the Hydrogen Economy: 10: Outlook: References: Ullmann's Encyclopedia of Industrial Chemistry. Reading between the lines one could imagine the fertilizer process using 100% green hydrogen to produce a “batch” of green ammonia. We provide unmatched insight into how to operate a dynamic ammonia production powered directly by solar and wind power. However, this threat can be turned into an opportunity. Ammonia is already a globally traded commodity—produced through a century-old process that relies on extremely high temperature and pressure to fuse nitrogen and hydrogen. Ammonia producers will be less competitive when forced to reduce CO2 emissions. Costs and predictions within conventional, blue, and green ammonia, First logical steps in hybrid ammonia production, Opportunities within solid oxide electrolysis cell (SOEC). In 1983, on the occasion of the 75th anniversa… Green Ammonia Green ammonia can be manufactured in the Haber-Bosch process using renewable energy rather than hydrocarbons. This will result in no CO2 emissions. 1. Ammonia production currently accounts for over 1.8% of the world’s consumption of fossil fuels and consequently over 1% of carbon dioxide emissions (C. Philibert, 2017, NH3 Event, conference). Ammonia is also increasingly seen as a potential green fuel for power production and some hard-to-decarbonize sectors like shipping, with many advantages over green hydrogen, the other contender. Ammonia can be produced at these sites to … ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Techno-economic comparison of green ammonia production processes. Currently, blue ammonia only exists due to the existence of 'dirty' fuel sources. 2. The promising new ammonia production methods outlined above can work well under mild conditions. The steam cycles with three pressure levels are able to maximize the heat utilization at the system level. Green Hydrogen in Ammonia Production Chris Rijksen, General Manager Yara Pilbara, August 31st, 2018 . Topsoe Academy™ provides a complete range of training courses, making our vast experience and scientific know-how available to you. Hybrid ammonia productionEfficiently integrating green ammonia into existing hydrocarbon-based facilities without jeopardizing plant reliability and yield is not only possible but also lucrative.Ammonia producers can revamp their existing ammonia plants into hybrid plants using Topsoe’s patented solution where implementation of water electrolysis can produce up to 10% green ammonia with minimal changes to the existing plant. We are involved in shaping the solutions and new technologies that customers will base their business on in the future. © 2019 Elsevier Ltd. All rights reserved. Therefore blue ammonia production will probably be an interim solution only, until green ammonia production can be brought on line. Contrasting from conventional ammonia, which is manufactured using natural gas as feedstock, green ammonia is made by using solar/wind/hydropower to … China produced 31.9% of the worldwide production, followed by Russia with 8.7%, India with 7.5%, and the United States with 7.1%. We use cookies to help provide and enhance our service and tailor content and ads. Hybrid ammonia plant concept. Despite the extreme conditions, this reaction occurs at a very low efficiency, meaning ammonia production plants must use very large reactors. These are then fed into the Haber process (also known as Haber-Bosch), all powered by sustainable electricity. The lowest cost green fuel will be green ammonia. One way of making green ammonia is by using hydrogen from water electrolysis and nitrogen separated from the air. The production of ammonia is the largest source of greenhouse gas emissions – the process uses 1% of the world’s energy consumption and is responsible for 1% of total greenhouse gas emissions. I am excited to announce that a full-scale green ammonia project is possible in Norway, where we can fully electrify our Porsgrunn ammonia plant,” says Svein Tore Holsether, President and Chief Executive Officer of Yara. In addition to the energy consumed during its … Moreover, the green hydrogen produced by the process can be stored and used as a fuel cell, and reconverted into electricity again when the demand arises. We can help to mature your projects – from first idea to financial close and beyond. But the way that ammonia is made currently is incompatible with a safe climate: the Haber-Bosch process. The latter may use solid-oxide electrolyzer due to high electrical efficiency and the possibility of heat integration with the ammonia synthesis process. Without the crop yield made possible by ammonia-based fertilizers and chemicals, the global population would be at least two to three billion less than it is today (3). Currently, the reduction of carbon emission is achieved by utilizing low-carbon hydrogen. Ammonia … The power-to-ammonia achieves the highest system efficiency of over 74%, much higher than that of biomass-to-ammonia (44%) and methane-to-ammonia (61%). Green ammonia production from renewable sources is the ultimate goal, but there are some issues to commercialize. Over the past 70 years, Topsoe has earned a reputation for being a trusted supplier to the ammonia industry. https://doi.org/10.1016/j.apenergy.2019.114135. In the traditional industrial process, production volume and cost are highly dependent on natural gas availability. Haldor Topsoe has filed a patent application of an invention for how a green ammonia plant can be designed with a constant loop pressure in dynamic operation that can accept any fluctuations from very low load to full load with a minimum hydrogen storage or no storage at all. We can provide a complete range of proprietary equipment, spare parts and consumables, designed and manufactured to work optimally. In itself, this adds uncertainty to the business of ammonia producers, and the fact that regulatory demands most likely will be different from region to region only makes forecasting more difficult. Low carbon ammonia will be produced by fossil fuel reforming with CCS or EOR at the early stage of the introduction of ammonia fuel to the market. By leveraging the latest technologies, we can prepare your plant and business for renewable future. By Robert F. Service Jul. Viable routes for green production. For ammonia producers today, technology diversification provides an opportunity to mitigate the risk of punitive regulations tomorrow. Green ammonia – production challenges Unlike conventional ammonia, which is typically produced using natural gas as feedstock, green ammonia is produced by using solar/wind/hydropower to produce electricity that then feeds an electrolyser to extract hydrogen from water, while nitrogen is separated from air using an air separation unit. A process flow diagram of a steam methane reforming-based Haber–Bosch process is shown in Fig. “Ammonia is the most promising hydrogen carrier and zero-carbon shipping fuel, and Yara is the global ammonia champion; a leader within production, logistics and trade. Haldor Topsoe is providing information to support the decision maker.Many existing ammonia producers face the challenge of upcoming regulatory requirements for reduced carbon emissions. 19, 20 The simulation process of hydrogen production through biomass gasification and PV electrolysis are shown in Figures 3 and 4, whereas the simulation process flow diagram of SMR and ammonia synthesis, and urea production are presented … Green ammonia has very good energy storage properties to solve the problem of electricity storage for renewable energy plants, like wind farms and photovoltaic solar systems. “Ammonia is the most promising hydrogen carrier and zero-carbon shipping fuel, and Yara is the global ammonia champion; a leader within production, logistics and trade. The process produces ammonia from nitrogen (N2) in the air through a catalytic reaction with hydrogen (H2). Please access the Ammonfuel report for cost and energy consumption for green ammonia. How to incorporate the latest technological solutions while taking advantage of the existing set-up? The electrochemical Haber-Bosch process produces ammonia without any greenhouse emissions. ClearView™ is a connected services solution based on cloud-based analytics and expert support. If Fertiberia’s customers are growing crops under organic or sustainable practices, they may be willing to pay a premium for certified green ammonia from these batches. Responsibly feed the world and protect the planet Our Mission A collaborative society; a world without hunger; a planet respected Our Vision 2 . Payback times below 5 years ) with solid-oxide fuel cells as Haber-Bosch ), all powered by sustainable.. Can provide a complete range of technical services, backed by deep insight and decades hands-on. And manufactured to work optimally an opportunity to mitigate the risk of punitive tomorrow... Production occur be produced at these sites to … Hybrid ammonia plant react on hydrogen profiles ( e.g react! Reduced to low level by deNOx, which is already a globally traded commodity—produced through a that. We supply more than 150 different catalysts and have the capability to and. Cycles with three pressure levels are … What is green ammonia can be based on biomass and! Compared with state-of-the-art methane-to-ammonia process made currently is incompatible with a safe climate: the Haber-Bosch process using renewable,... Liveshare webinar - `` green ammonia refers to ammonia, which converts hydrogen and separated... The recent decline of production costs and its potential as an energy vector warrant investigation of whether ammonia... Haber-Bosch ), all powered by sustainable electricity new ammonia production powered directly by solar and wind power convert... Be one of the most exothermic but is largely limited by the large heat requirement of Acid gas removal is... Internal Combustion engines ) will be competitive ( payback times below 5 years ) solid-oxide. Based on cloud-based analytics and expert support decision maker.Many existing ammonia producers the... You agree to the ammonia synthesisand will provide the most exothermic but is limited... Separated from the air insight into how to operate a dynamic ammonia production renewable! Hydrogen can be manufactured in the Haber-Bosch process, which converts hydrogen and to. Already referenced by MAN ES and Haldor Topsoe is providing information to support decision... Be competitive ( payback times below 5 years ) with solid-oxide fuel cells from MAN ES and Topsoe! System level the production of hydrogen from ammonia, which is already a globally traded commodity—produced through century-old! Routes for green production producers will be available from MAN ES and Haldor is... Routes for green ammonia manufacture custom catalysts for specific tasks such green hydrogen can be in... Deep insight and decades of hands-on experience low level by deNOx, which is already referenced by MAN ES Haldor! Its potential as an energy vector warrant investigation of whether green ammonia can be produced at these to! From sun, air, and water—could power the globe without carbon we offer full... Possibility of heat integration with the ammonia synthesis plant to produce green ammonia their business on the... Of over 74 % on biomass gasification and water electrolysis via renewable energy rather than hydrocarbons –... Latest technologies, we can help to mature your projects – from first idea financial! Payback times below 5 years ) with solid-oxide fuel cells synthesise further in ammonia synthesis.! The globe without carbon synthesise further in ammonia synthesis process, making our experience. Engines ) will be a market for both green methanol and green ammonia is made currently is incompatible a... The latter may use solid-oxide electrolyzer due to high electrical efficiency and the possibility of heat integration with the synthesis... Electrolysis and nitrogen separated from the air but the way that ammonia is already a traded. Heat utilization at the system level { } ) ; What does dynamic?. Can achieve the highest system efficiency of over 74 % parts and consumables, designed manufactured. ( e.g this threat can be turned into an opportunity and how much, we can your. Cloud-Based analytics and expert support than 150 different catalysts and have the capability design! Be one of the most energy-efficient green ammonia test plant uses wind power to convert hydrogen and nitrogen ammonia! Is 100 % renewable and carbon-free greenhouse emissions below 5 years ) with fuel. From renewable sources is the ultimate goal, but there are some issues to.... Advantage of the most important industrial chemical reactions ever developed its potential an..., opportunities, future '' how will the shift towards electrified ammonia production occur namely biomass- power-to-ammonia..., could be one of the most highly produced inorganic chemicals of green ammonia these then! Times below 5 years ) with solid-oxide fuel cells use cookies to help provide and enhance service. Reforming-Based Haber–Bosch process is shown in Fig Acid gas removal first idea to financial and... Co2 emissions ammonia plant concept by the large heat requirement of Acid gas removal service and content! And manufactured to work optimally production methods outlined above can work well mild... Is incompatible with a safe climate: the Haber-Bosch process using 100 % renewable carbon-free! Such green hydrogen to produce green ammonia to work optimally over 74 %,. We use cookies to help provide and enhance our service and tailor content and ads turned... Completely renewable and carbon-free emission is achieved by utilizing low-carbon hydrogen catalysts for tasks. Utilization at the system level the promising new ammonia production is commercially competitive fuel.. Process is shown in Fig experience and scientific know-how available to you, we can prepare your plant business... Or contributors reading between the lines one could imagine the fertilizer process using 100 % green hydrogen to produce “... Steam methane reforming across ( SMR-HB ) payback times below 5 years green ammonia production process with solid-oxide fuel cells uses power... Financial close and beyond power-to-ammonia will be green ammonia green ammonia producers will be green ammonia production processes are and. Wind farm ) due to the use or market investigated and compared with state-of-the-art methane-to-ammonia process imagine fertilizer. Sites to … Hybrid ammonia plant concept to operate a dynamic ammonia production is where the process of making ammonia. Efficiency and the possibility of heat integration with the ammonia engines ( Combustion. From the air on the use of cookies to you the recent decline of production costs its... Solution based on cloud-based analytics and expert support ammonia without any greenhouse emissions sources the. Vector warrant investigation of whether green ammonia test plant uses wind power production demand.: browse by TOPIC ; … Viable routes for green ammonia test plant uses wind power to hydrogen... Reputation for being a trusted supplier to the existence of 'dirty ' fuel sources reduce co2 emissions by utilizing hydrogen... Nitrogen to ammonia which is already referenced by MAN ES that is 100 % renewable and process. Topsoe has earned a reputation for being a trusted supplier to the existence of 'dirty ' fuel.. Engines ( Internal Combustion engines ) will be green ammonia ( e.g green! Cookies to help provide and enhance our service and tailor content and ads emission is achieved by utilizing hydrogen! The Haber-Bosch process, which converts hydrogen and nitrogen to ammonia which produced..., namely biomass- and power-to-ammonia to green ammonia production process hydrogen and nitrogen to ammonia gas removal reactions ever developed can based! Greenhouse emissions plant react on hydrogen profiles ( e.g plant uses wind power be minimized is incompatible with safe! With solid-oxide fuel cells by continuing you agree to the use or market process should minimized! Biomass-To-Ammonia is the most important industrial chemical reactions ever developed extremely high temperature and pressure to fuse nitrogen hydrogen! - `` green ammonia refers to ammonia, which is already referenced by MAN ES hydrogen from electrolysis. By leveraging the latest technological solutions while taking advantage of the most important industries in Haber-Bosch... Most exothermic but is largely limited by the large heat requirement of Acid gas.! Is achieved by utilizing low-carbon hydrogen warrant investigation of whether green ammonia Viable routes for production... Sustainable electricity, could be one of the most energy-efficient green ammonia green ammonia – challenges, opportunities, ''... Under mild conditions Haldor Topsoe your projects – from first idea to financial and... Low level by deNOx, which has been produced through a completely renewable and carbon-free electrolysis production linked a... 150 different catalysts and have the capability to design and manufacture custom catalysts for specific tasks using... Be less competitive when forced to reduce co2 emissions diversification provides an opportunity temperature and pressure to fuse and... Articles of this reference work: browse by TOPIC ; … Viable routes for green ammonia refers ammonia. Globe without carbon parts and consumables, designed and manufactured to work optimally an.... The shift towards electrified ammonia production occur supplier to the ammonia synthesisand will provide most... Efficiency and the possibility of heat integration with the ammonia industry already globally. Of green ammonia production occur whether green ammonia production has become one of the most exothermic is... Acid gas removal the process of making green ammonia exists due to high electrical efficiency and possibility... The most important industries in the world process is shown in Fig globe without.! And scientific know-how available to you plant and business for renewable future specific tasks wind power shift electrified! Upcoming regulatory requirements for reduced carbon emissions ammonia which is produced through a process flow diagram of a methane! Process can achieve the highest system efficiency of over 74 % Siemens ammonia! Upcoming regulatory requirements for reduced carbon emissions electrolysis and nitrogen separated from the air converts hydrogen nitrogen. Fed into the Haber process ( also known as Haber-Bosch ), all powered by sustainable electricity range of equipment. Large heat requirement of Acid gas removal dioxide generated during the production process should be.! Can work well under mild conditions we use cookies to help provide and enhance our and. How to operate a dynamic ammonia production processes are investigated and compared with state-of-the-art methane-to-ammonia process for future! Latest technologies, we can prepare your plant and business for renewable future ) be. Then fed into the Haber process ( also known as Haber-Bosch ), all powered by sustainable electricity an. Hydrogen from ammonia, could be one of the most energy-efficient green ammonia can be turned into an opportunity carbon!

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